Silicone

Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer

INCI: SILICONE QUATERNIUM-16/GLYCIDOXY DIMETHICONE CROSSPOLYMER

Reviewed by Emma · Last updated 2 Jun 2026

Also known as: Silicone Quaternium-16/glycidoxy Dimethicone Crosspolymer

A silicone polymer that conditions and smooths the hair shaft

Addresses

Frizz

Usage Frequency

Daily

What Is Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer?

Silicone Quaternium-16/Glycidoxy Dimethicone Crosspolymer is a synthetic polymer derived from silicone chemistry. It belongs to a class of conditioning agents designed to coat and protect hair fibres, combining both silicone and quaternary ammonium components to enhance adhesion and performance.

This ingredient is primarily used in hair care formulations rather than skincare. It functions as a conditioning and film-forming agent, depositing a protective layer on the hair surface to improve texture, shine, and manageability.

How It Works

The ingredient works by forming a thin, continuous film along the hair shaft. The silicone component provides a hydrophobic (water-repellent) coating, whilst the quaternary ammonium groups help the polymer adhere firmly to the hair surface through electrostatic attraction.

This dual mechanism means the conditioning benefits persist through washing and styling, rather than rinsing away immediately. The crosslinked polymer structure also helps it withstand heat and mechanical stress.

Clinical Evidence & References

Research specific to this particular crosspolymer formulation is limited in the published literature. However, silicone-based conditioning polymers in general have a long history of use and are well-established for their ability to improve hair feel, appearance, and combability in both laboratory testing and consumer studies.

The conditioning and film-forming properties of silicone quaterniums are widely accepted within the cosmetic chemistry field, though individual formulations vary in their performance depending on concentration and supporting ingredients.

How to Use

This ingredient is typically found in rinse-off hair conditioners, leave-in treatments, and styling products. When present in a formula, it usually remains on the hair after rinsing and builds up with repeated use. If you find your hair becomes weighed down over time, consider using a clarifying shampoo periodically to remove accumulated silicone deposits.

Safety & Precautions

Silicone-based conditioning polymers are generally well-tolerated and have a long safety history in cosmetics. Some people report that silicone buildup on hair can occur with frequent use, though this is a cosmetic concern rather than a safety issue.

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