Silicone

Polypropylsilsesquioxane

INCI: POLYPROPYLSILSESQUIOXANE

Reviewed by Rosie · Last updated 14 Aug 2026

A silicone polymer that creates a smooth, protective film on skin

Best For Skin Types

All, Oily, Combination, Mature

Addresses

Fine lines, Dryness, Pore minimising

Usage Frequency

Daily

What Is Polypropylsilsesquioxane?

Polypropylsilsesquioxane is a synthetic silicone polymer derived from silica. It belongs to the silsesquioxane family of ingredients and is used primarily in cosmetics for its film-forming properties.

When applied to skin, it forms a thin, continuous layer that sits on the surface. This film is designed to improve the feel and appearance of products whilst creating a light protective barrier. It is used in roughly 0.5% of skincare formulations.

How It Works

Polypropylsilsesquioxane works by polymerising on the skin surface to form a cohesive, lightweight film. Unlike heavier silicones, this polymer is designed to be breathable whilst still providing a protective layer.

The film smooths micro-irregularities on skin, which can optically reduce the visibility of texture and fine lines. It also slows moisture evaporation from the stratum corneum without fully sealing the skin, making it suitable for use on most skin types.

Clinical Evidence & References

Published clinical data specifically on polypropylsilsesquioxane alone is limited. However, silicone polymers as a class have been extensively studied and are generally recognised as safe and effective for film-forming applications in skincare.

Evidence supports the use of silicone-based films for temporary texture smoothing and barrier support. Most claims centre on sensory benefits and short-term appearance improvements rather than long-term skin health outcomes. Further research would help clarify its efficacy in specific skincare contexts.

How to Use

Polypropylsilsesquioxane is typically found in primers, serums, and lightweight moisturisers. Apply over clean skin or after other actives to allow the film to set. It can be layered under makeup or used alone. Remove with a gentle cleanser in the evening, as the film should not be left on skin overnight.

Safety & Precautions

Polypropylsilsesquioxane is generally well-tolerated and non-comedogenic in most formulations. It is not known to trigger sensitivity or allergic reactions in the general population, though individuals with silicone sensitivities should patch-test first.

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