Silicone

PEG-40 …

INCI: PEG-40/PPG-8 METHYLAMINOPROPYL/HYDROXYPROPYL DIMETHICONE COPOLYMER

Reviewed by Emma · Last updated 14 Aug 2026

Also known as: Peg-40/ppg-8 Methylaminopropyl/hydroxypropyl Dimethicone Copolymer

A silicone-based conditioning polymer that smooths and protects hair

Usage Frequency

Daily

What Is PEG-40 …?

PEG-40/PPG-8 Methylaminopropyl/Hydroxypropyl Dimethicone Copolymer is a hybrid polymer that combines silicone chemistry with polyethylene glycol (PEG) and polypropylene glycol (PPG) components. It is a synthetic compound designed to condition and protect fibres, most commonly used in hair care formulations.

This ingredient forms a thin, protective layer on the surface of hair, helping to seal the outer cuticle and reduce moisture loss. Its structure allows it to provide both hydrophobic (water-repelling) and hydrophilic (water-attracting) properties, making it versatile in different product types.

How It Works

This copolymer works by depositing a thin, continuous film over the hair surface. The silicone component provides hydrophobic conditioning, whilst the PEG and PPG components help ensure even distribution and compatibility with water-based formulations. This dual nature allows the ingredient to coat hair effectively without the heavy or greasy feel sometimes associated with pure silicones.

The polymer's molecular structure also enables it to bind to damaged or porous areas of the hair, helping to fill microscopic gaps in the cuticle and restore a smoother surface texture.

Clinical Evidence & References

Direct clinical research on this specific ingredient is limited in published literature. However, silicone-based conditioning polymers are well-established in cosmetic chemistry and have a long history of safe use in hair care products.

The conditioning effects—smoothing, shine enhancement, and reduced breakage—are consistent with the known behaviour of similar silicone copolymers used in the industry. Evidence for these benefits comes primarily from formulation science and consumer perception studies rather than rigorous clinical trials.

How to Use

This ingredient is typically used in rinse-off products such as conditioners and hair masks, where it can be applied directly to hair strands and then washed away. In leave-on formulations, use sparingly to avoid product build-up over time. For best results, apply to mid-lengths and ends of hair rather than the scalp, which may already produce natural oils.

Safety & Precautions

This ingredient is generally well-tolerated and has a long safety history in cosmetic use. It is not typically a sensitiser, though individuals with silicone sensitivity or those prone to product build-up may wish to rotate products or use clarifying treatments periodically.

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